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On the verge of his long-awaited wedding to Angelina Jolie, it’s not the best time for Brad Pitt to be awash in rumors about another woman. “He’s been spending a lot of time with a woman who’s been seen with him on and off the set,” a source confirms to OK!, referring to his current project, World War Z, in Malta. “And word is that Angelina is paranoid about her — she’s drop-dead gorgeous, and I’m sure Angie’s determined to find out what’s going on between them.”

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As he’s been in a relationship with Angelina since 2005, could Brad be suffering from the seven-year itch a little early? Indeed, the situation is playing out right under Angelina’s nose: She’s in Malta, bunking in a rented 8th-century palace with Brad and their six kids (Maddox, Pax, Zahara, Shiloh, Knox and Vivienne), the ones who have been pushing Mom and Dad to make the relationship legal. Brad’s film has been billed as an apocalyptic thriller.

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Does his new friendship spell doomsday for a Jolie-Pitt wedding? “Their marriage plans haven’t been discussed for a few weeks now,” the source reveals. “And it’s quite a coincidence that they’re being pushed back right when Brad is getting close to another woman.”

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And, just as her own behavior was once described by Brad’s ex-wife Jennifer Aniston, Angelina finds Brad’s connections with other women “not cool.”

“She has a problem with any other woman who’s in Brad’s life,” the source says. “She hates the fact that he keeps in touch with Jen.” (A month ago, it was reported that Brad contacted Jen with condolences on the death of her dog, Norman, for example.)

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Ironically, this rift comes when the world’s most glamorous (and traditionally private) couple have been spilling on their relationship like drunken starlets.“I love being with Brad,” Angie said recently, calling him “a gentleman” and gushing that “physically he’s a real man… in all the things that it means.”

FOR MORE ON BRAD’S FLIRTATIOUS WAYS, PICK UP THIS WEEK’S ISSUE OF OK! – ON SALE EVERYWHERE NOW!

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