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Those eagerly awaiting a post-pregnancy Jessica Simpson sighting will finally get their wish on Sept. 10.

OK! GALLERY: JESSICA SIMPSON IN THE BIG APPLE

The new mother is slated to kick off Katie Couric's new talk show as her first guest, where the entrepreneur and entertainer will make her first official TV comeback discussing all of her major changes in the past year.

The Weight Watchers spokesperson (who inked a $4 million deal) will open up about her weight loss challenges and how she balances motherhood, her relationship and a billion dollar clothing and accessories company.

Meanwhile, Jess Tweeted about wrapping her first Weight Watchers commercial on August 16, how she's given up booze (Jessica was a major Scotch fan) for water and gifted all the girls in her weight loss club with pedometers to track their steps.

OK! GALLERY: JESSICA SIMPSON KEEPS ROCKING HER BABY BUMP

"What we put in our bodies mirrors our Self-Worth! " she wrote.

Musician Sheryl Crow will also pop in as a guest on Katie's kick-off show, which will air on Sept. 10, 3 pm EST on ABC.

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