The 29-year-old actress looked positively whimsical in her full tulle Valentino gown that billowed in the soft evening breeze at the outdoor ceremony just as the sun was setting.
Anne wore a matching vintage head piece and long veil that gave her an ethereal look and covered up her short pixie cut.
The off-the-shoulder bodice had delicate embroidery and the Rachel Getting Married star held a small bunch of flowers as she said her "I do's" with her handsome groom.
Legendary designer Valentino Garavani gushed to E! News that The Dark Knight Rises star is "a very good friend of mine" and was thrilled to be the one to create the most important gown of her life.
"She's like my daughter!" the popular fashion star added.
Anne's big day was held at a private house in Big Sur in front of over 100 guests and was surrounded by homey and rustic decor.
"It was just friends and family," a source told People. "No movie stars. There were only a few people in the business there, like her stunt double."
The images show just how in love and affectionate Anne and Adam are with each other and the proud groom helped his bride with her dress and catered to his lady love's every need throughout the day.
The reception was just as fun and intimate and featured an all-vegan menu, like what they served at their engagement party in New York earlier this year.
Guests inhaled the dizzying smell of $100,000 worth of flowers and danced the night away to songs from the San Francisco-based jazz trio Americano Social Club.
Anne, Adam and their family and friends had a full weekend of celebration including a rehearsal dinner on Friday and all organized by event planners Yifat Oren and Stefanie Cove who also were at the helm of Natalie Portman's nuptials earlier this year.
Anne is hitting the big screen again in the film adaptation of Les Miserables which co-stars Hugh Jackman and comes out on Christmas Day.
What do you think of Anne's wedding dress?