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Leighton Meester beamed bright in black as she promoted Herbal Essences hair products today at the Hesperia Hotel in Madrid, Spain. The Gossip Girl beauty rocked her tousled tresses as she hammed it up for the camera in a black mini dress and fun open-toed pumps! Leighton has a lot on her plate with filming GG, endorsement deals and promoting her new flick, Country Strong!

OK! GALLERY: COUNTRY STRONG BRINGS OUT THE BIG STARS IN NASHVILLE

Not only is Leighton campaigning with Herbal Essences, but Vera Wang just signed the star to a two-year, $3 million deal to be the face of her new fragrance (out this summer).

After spotting this sneak peek of Leighton filming the commercial, we know one thing’s for sure: If the perfume’s half as great as this dress, it’ll be a winner!

OK! NEWS: LEIGHTON MEESTER’S $3 MILLION GLOW

Country Strong hits theaters nationwide on Jan. 7, but if you’re lucky enough to live in L.A. or Nashville you can see it early on Dec. 22!

The film is centered around a an aging country star, played by Gwyneth Paltrow, who starts to feel overtaken by a young, promising talent, portrayed by Leighton.

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