The couple, who has been married since 2012, looked extra stylish at the premiere. Matthew, 49, wore a dark brown suit and a slightly unbuttoned white dress shirt with brown leather shoes.
Camila, 36, looked gorgeous in a fitted, white dress that she paired with a fun Zebra pea coat that fell right below her knees. She added black heels and a matching black cross body bag that featured a gold chain.
Anne, 36, looked great in a black turtleneck that she had tucked into a gorgeous black, blue and green maxi skirt. She completed her look with pointed black suede pumps and held some of her essentials in a small black clutch.
Diane, 54, opted to wear a black monochromatic outfit that consisted of a tuxedo high-low blazer, a scoop neck t-shirt and black slacks. She added leather boots and accessorized with minimal jewelry.
Serenity premieres in U.S theaters on Friday, January 25.
Whose outfit from the premiere do you like best? Let us know in the comments below!