The actress appeared to be on mom duty, as she let the youngster push the cart around while walking beside her. Wrapped in a comfy cardigan, Jolie kept her long locks down while she and Vivienne wore face masks in the store.
The mother-daughter sighting comes as the estranged couple's divorce proceedings rage on.
Despite Jolie recently taking home a small victory — as she was finally able to sell her share of the $164 million French Chateau she co-owns with her ex — the former Hollywood couple has a long way to go in tying up the loose ends of their split.
Ever since the brunette beauty filed for divorce from Pitt in 2016 and requested primary custody of five of their six kids: Pax, 17, Zahara, 16, Shiloh, 15, and twins Vivienne and Knox, 13, things between the two have been messy — to say the least. (The former flames also share 20-year-old son Maddox, who is legally considered an adult.)
Pitt, 57, previously secured a win in their court battle last June when Judge John Ouderkirk granted him joint custody. However, the lawyers for Pitt's Mr. & Mrs. Smith costar argued that the judge failed to disclose he had previous relationships with the handsome hunk's team.
A California appeals court then disqualified the private judge, meaning Ouderkirk's decision could now be thrown out — which still wouldn't guarantee a win for Jolie. "She’s still got an uphill battle because now there is historical observation rather than future projection [of how the children are doing]," an insider previously explained of the current situation.
Pitt took another hit last month when his petition to review Ouderkirk's exit was denied.
Meanwhile, the Maleficent actress, 46, has also been opening up about the former famed couple's rocky marriage, with her claiming in September that she feared for their children's safety. The duo abruptly called it quits in 2016 following an alleged incident where Pitt was “verbally abusive and physical” with their adopted son on a private flight from France to Los Angeles.
While the co-parents' messy divorce may be far from over, Jolie has been enjoying her time with five of her six kiddos as they jet around the world for the premieres of her upcoming film Eternals. (Pax hasn't attended his mom's movie premieres, as he's reportedly studying biochemistry at Yonsei University in Seoul, South Korea.)
Scroll through to see photos of Jolie and her daughter taking a trip to the grocery store.
The doting mother-of-six and her little one were seen browsing the aisles at Gelson's Supermarket.
Jolie and Vivienne were being very affectionate during their one-on-one time together.
The duo reportedly shopped around for about 40 minutes before checking out and bagging their own groceries.